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Melting and boiling

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Changing states

Matter can change from one state to another when it gains or loses energy. Ice turns to water, water turns to steam. These changes are physical changes: the substance is still the same substance.

The particle model

State Particles Energy
Solid Packed tightly in fixed positions; vibrate in place Lowest
Liquid Close together but can slide past each other Medium
Gas Far apart, moving fast in all directions Highest

Heating gives particles more energy, so they move faster. Cooling takes energy away, so they slow down.

Melting

Melting is the change from solid to liquid. As a solid is heated, its particles vibrate more and more. At the melting point, they vibrate so much they break free of their fixed positions and start to slide past each other.

Substance Melting point
Ice (water) 0 °C
Chocolate About 30–35 °C (that’s why it melts in your mouth!)
Candle wax About 50–70 °C
Lead 327 °C
Iron 1538 °C
Tungsten 3422 °C (highest of any metal)

Freezing is the opposite of melting. For a pure substance, the freezing point and the melting point are the same temperature.

Boiling

Boiling is the rapid change from liquid to gas. At the boiling point, particles have enough energy to escape from all through the liquid, forming bubbles of gas.

Substance Boiling point (at sea level)
Liquid nitrogen −196 °C
Rubbing alcohol 82 °C
Water 100 °C
Cooking oil Above 300 °C (it smokes and burns before boiling)

Boiling point and air pressure

Boiling point depends on air pressure. High in the mountains, the air pressure is lower, so water boils at a lower temperature. On top of Mount Everest, water boils at only about 70 °C, which makes it hard to cook pasta! A pressure cooker does the opposite: it raises the pressure so water boils above 100 °C, cooking food faster.

Evaporation vs. boiling

Evaporation Boiling
Happens at any temperature Happens only at the boiling point
Only at the surface Throughout the liquid
Slow Fast
Cools the liquid left behind Temperature stays constant

Sweating cools you because evaporating sweat carries heat away from your skin.

The heating curve

If you heat ice from −20 °C until it becomes steam, the temperature doesn’t rise steadily.

Stage What happens to temperature
Ice warms Rises from −20 °C to 0 °C
Ice melts Stays at 0 °C until all ice is melted
Water warms Rises from 0 °C to 100 °C
Water boils Stays at 100 °C until all water is gas
Steam warms Rises above 100 °C

During melting and boiling, the energy goes into breaking particles apart, not into making them move faster. This hidden energy is called latent heat. That’s why a glass of ice water stays at about 0 °C until the ice is gone.

Other changes of state

Change From → To Example
Condensation Gas → liquid Water drops on a cold glass
Sublimation Solid → gas Dry ice making fog
Deposition Gas → solid Frost forming on a window

Impurities change melting and boiling points

Adding salt to water lowers its freezing point and raises its boiling point. That’s why salt melts ice on roads in winter (it works down to about −10 °C). Pure substances have sharp melting points, so scientists use melting points to test purity.

Common mistakes

  • Thinking bubbles in boiling water are air. They’re water vapour.
  • Thinking temperature keeps rising while ice melts.
  • Thinking steam is visible. The white cloud is tiny water droplets; real steam is invisible.

Try it yourself

  1. Heat ice in a pot (with an adult) and record the temperature every 30 seconds until the water boils. Graph your results.
  2. Put one ice cube on a plate with salt and one without. Which melts faster?
  3. Wet two paper towels; hang one in the sun and one in the shade. Which dries first?

Quick recap

  • Melting turns solids into liquids; freezing does the reverse.
  • Boiling happens throughout a liquid at its boiling point; evaporation happens at the surface.
  • Boiling points change with air pressure.
  • Temperature stays the same during a change of state because of latent heat.
  • Impurities like salt change melting and boiling points.